For other uses of Brittle, see Brittle (disambiguation).

A material is brittle if it is subject to fracture when put under stress or strain. This fracture absorbs relatively little energy, even in materials of high strength.

When used in materials science, it is generally applied to materials that fail in tension rather than shear, or when there is no evidence of plastic deformation before failure.

When a material has reached the limit of its strength, it usually has the option of either deformation or fracture. A naturally malleable metal can be made stronger by impeding the mechanisms of plastic deformation (reducing grain size, dispersion strengthening , work hardening, etc.), but if this is taken to an extreme, fracture becomes the more likely outcome, and the material can become brittle. Improving material toughness is therefore a balancing act.

This principle generalizes to other classes of material. Naturally brittle materials, such as ceramics (most famously glass), are difficult to toughen effectively. Most such techniques involve one of two mechanisms: to deflect the tip of a propagating crack, for instance by introducing natrual weaknesses of limited extent, or to create carefully controlled residual stresses so that cracks from certain predictable sources will be forced closed, as in the case of toughened glass and pre-stressed concrete. Both mechanisms tend to soften the material somewhat, although most ceramics are quite hard to begin with. The least-brittle structural ceramics are silicon carbide (mainly by virtue of its high strength) and transformation-toughened zirconia.