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Formox process

Formox process produces fromaldehyde.

Industrially formaldehyde is produced by the catalytic oxidation of methanol. The most commonly used catalysts are silver metal or a mixture of an iron oxide with molybdenum and vanadium. In the more commonly used iron oxide system (Formox process), methanol and oxygen react at 400°C to produce formaldehyde according to the chemical equation

CH3OH + ½ O2 → H2CO + H2O

The silver-based catalyst is usually operated at a higher temperature, about 650°C. On it, two chemical reactions simultaneously produce formaldehyde: the one shown above, and the dehydrogenation reaction

CH3OH → H2CO + H2

Further oxidation of the formaldehyde product during its production usually gives formic acid that is found in formaldehyde solution, found in ppm values.

10-26-2009 08:16:03
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