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Benzenediols

(Redirected from Resorcinol)

Benzenediols or dihydroxybenzenes are aromatic chemical compounds in which two hydroxyl groups are substituted onto a benzene ring. Because they have at least one hydroxyl group covalently bonded directly to a carbon atom in a benzene ring, they are in a class of organic compounds called phenols. There are three isomers of bezenediol, each of which has its own common or non-systematic name as shown in the mini-table below. Various other ways of naming these three chemical compounds are also shown:

ortho
isomer
meta
isomer
para
isomer
1,2-benzenediol
o-benzenediol
1,2-dihydroxybenzene
o-dihydroxybenzene
chatechol

pyrochatechol
1,3-benzenediol
m-benzenediol
1,3-dihydroxybenzene
p-dihydroxybenzene
resorcinol

1,4-benzenediol
p-benzenediol
1,4-dihydroxybenzene
p-dihydroxybenzene
hydroquinone

All three of these compounds are colorless to white granular solids at room temperature and pressure, but upon exposure to oxygen they may darken. All three isomers have the chemical formula C6H6O2. The chemical structures are shown here:


Similar to other phenols, the hydroxyl groups on the aromatic ring of a benzenediol are weakly acidic. Each benzenediol can lose an H+ from one of the hydroxyls to form a monophenolate ion or lose an H+ from both to form a diphenolate ion.


Urushiols are naturally existing organic compounds which have the catechol skeleton structure and diphenol functionality but with alkyl groups substituted onto the aromatic ring. Urushiols are the skin-irritating poisons found in plants like poison ivy, etc. Two parts of a molecule of catechin, another natural compound which is used for tea, have the catechol skeleton structure in it.

Both hydroquinone and catechol have been used as film developing chemicals. The use of hydroquinone for film developing is common.

Hydroquinone can undergo mild oxidation to convert to the compound parabenzoquinone, C6H4O2, often called p-quinone or simply quinone. Reduction of quinone reverses this reaction back to hydroquinone. Some biochemical compounds in nature have this sort of hydroquinone or quinone section in their structures, such as Coenzyme Q, and can undergo similar redox interconversions. Hydroquinone has a variety of uses principally associated with its action as a reducing agent which is soluble in water. It is a major component in most photographic developers where, with the compound Metol, it reduces silver halides to elemental silver. Catechol has also been used as film developing chemical.

In human medicine, hydroquinone also used as a topical application to reduce the color of skin. It does not have the same predisposition to cause dermatitis as Metol does.

10-26-2009 08:16:03
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